extraction and stripping of molybdenum and rhenium

extraction and stripping of molybdenum and rhenium

Solvent extraction of rhenium from molybdenum in

2009. 7. 1. Molybdenum and rhenium were stripped by Ammonia liquor (18%) solution at an aqueous/organic phase ratio of 1:1. After the stripping, the organic phase was regenerated by treatment with 10% sulphuric acid and was subsequently used for the extraction of molybdenum and rhenium.

Behavior of Extraction, Stripping, and Separation Possibilities of

possibility of selective stripping of rhenium and molybdenum using several stripping agent such as NH 4OH (10 to 50 vol%), NaCl (1 to 5kmol/m3) and HNO 3 (1 to 5kmol/m3). The stripping behavior of rhenium and molybdenum with different concentration of HNO 3 (in the range of 1 to 5 kmol/m3) as a stripping solution was examined while

Separation of molybdenum and rhenium by extraction with

1979. 1. 1. Molybdenum can be selectively stripped by ammonia or ammonium salts to give an aqueous phase containing 60 g/l Mo and 0.01 g/l Re. Rhenium may then be stripped from the resulting organic phase with 8 M nitric acid to give an aqueous solution containing 7 g/l Re and 0.15 g/l Mo. INTRODUCTION Several methods of separating molybdenum and rhenium by solvent extrac- tion

Behavior of Extraction, Stripping, and Separation

The main objective of the present study is to separate the rhenium and molybdenum as well as recovery of the targeted metal ion. The behavior of extraction, stripping and separation possibilities of rhenium and molybdenum from molybdenite roasting dust leaching solutions using tri-otyl-amine (TOA) as an extractant has been investigated.

How to Separate Recover Molybdenum Rhenium

2021. 1. 5. Molybdenum and rhenium can be extracted and separated from an electrooxidation pregnant solution by a combined process utilizing solvent extraction, carbon adsorption, and crystallization. Byproduct recovery of precious metals and

Solvent extraction of molybdenum (VI), tungsten (VI) and

2001. 3. 1. Metals were stripped by ammonia (1:1) solution at an aqueous/organic phase ratio of between 1:1 and 1:2. After the stripping, the organic phase was regenerated by treatment with 10% sulphuric acid and was subsequently used for the extraction of molybdenum and rhenium.

Solvent extraction of rhenium from molybdenum in

Abstract The of selective extraction of rhenium from alkaline solutions containing rhenium and molybdenum by solvent extraction using a mixture of tributyl phosphate and triotylamine as extractant has been investigated, complete separation of rhenium from alkaline solutions containing rhenium and molybdenum was possible after repeated extraction and repeated stripping.

US3751555A Solvent extraction process for the recovery

process for the recovery of molybdenum and rhenium values from highly acid solutions which comprises contacting the solution with a water-immiscible organic phase including a mixed extractant comprising an alkyl phosphonate and an organophosphoric acid with or without the addition of an amine extractant, or first contacting the solution with the phosphonate to selectively remove rhenium,

Recovery and Separation of Molybdenum and Rhenium

Recovery and separation of molybdenum and rhenium from a process solution was accomplished by a technique developed by the Federal Bureau of Mines involving a combined solvent extraction and activated carbon adsorption procedure. The processing sequence required treatment of the solution with SO2 to reduce the chlorate ion and adjust the pH prior to solvent extraction of molybdenum and rhenium

Solvent extraction of rhenium from molybdenum in

Abstract The of selective extraction of rhenium from alkaline solutions containing rhenium and molybdenum by solvent extraction using a mixture of tributyl phosphate and triotylamine as extractant has been investigated, complete separation of rhenium from alkaline solutions containing rhenium and molybdenum was possible after repeated extraction and repeated stripping.

US3751555A Solvent extraction process for the

process for the recovery of molybdenum and rhenium values from highly acid solutions which comprises contacting the solution with a water-immiscible organic phase including a mixed extractant comprising an alkyl phosphonate and an organophosphoric acid with or without the addition of an amine extractant, or first contacting the solution with the phosphonate to selectively remove rhenium

Recovery of Molybdenum Rhenium From

2017. 5. 22. Molybdenum-rhenium extraction was unaffected by presence of chalcopyrite in the molybdenite concentrate; however, molybdenum extraction declines if the copper content, as chalcocite, exceeds 7 pct. High-purity molybdenum and rhenium compounds can be recovered from the electrolyzed reaction mass by liquid-solid separation, solvent extraction

US3681016A Recovery of rhenium and molybdenum

a process for recovering rhenium and molybdenum values from solution comprising: extracting the soluble molybdenum and rhenium values with an amine solvent, stripping the values from the amine extract with an ammonium hydroxide solution, purifying the strip solution of copper, iron, silicon, phosphorous, and arsenic, crystallizing the molybdenum as ammonium tetramlybdate containing a

Recovery and Separation of Molybdenum and Rhenium

Recovery and separation of molybdenum and rhenium from a process solution was accomplished by a technique developed by the Federal Bureau of Mines involving a combined solvent extraction and activated carbon adsorption procedure. The processing sequence required treatment of the solution with SO2 to reduce the chlorate ion and adjust the pH prior to solvent extraction of molybdenum and rhenium

Separation and Puriﬁcation Technology

Rhenium Molybdenum Roasting ﬂue-dust TBP Solvent extraction ABSTRACT The selective extraction of rhenium from the leach liquor of molybdenite roasting ﬂue-dust and its subsequent stripping were investigated using the solvent extraction

Selective Recovery of Molybdenum over Rhenium from Molybdenite

2020. 11. 4. Abstract: Selective solvent extraction of molybdenum over rhenium from molybdenite (MoS2) ﬂue dust leaching solution was studied. In the present work, thermodynamic calculations of the chemical equilibria in aqueous solution were ﬁrst performed, and the potential–pH diagram for the Mo–Re–SO2 4 –H2O system was constructed.

Recovery of molybdenum and rhenium in scrub liquors

Abstract The present work addresses the recovery of rhenium from scrub liquor of molybdenite concentrate roasting fume and dust by solvent extraction method. According to the results, recovery of rhenium from the scrub liquor is not practical unless molybdenum is removed in advance. The extraction of molybdenum was carried out using a D2EHPA-TBP system which resulted in up to

Extraction of molybdenum by a supported liquid membrane

2014. 3. 12. Extraction of molybdenum by a supported liquid membrane method Carlos Basualtoa,*, Jose´ Marcheseb, Fernando Valenzuelaa, Adolfo Acostab a Lab. Operaciones Unitarias, Fac. Ciencias Quı´micas y Farmace´uticas, Universidad de Chile, CC 233, Santiago, Chile b Laboratorio de Ciencias de Superﬁcie y Medios Porosos, Dpto de Quı´mica, UNSL-FONCYT, C.C.256-5700, San Luis, Argentina

(PDF) Extraction of molybdenum by a supported liquid

Extraction of molybdenum by a supported liquid membrane method. Fernando Valenzuela. Related Papers. Transport of molybdenum with Alamine 336 using supported liquid membrane. By Fernando Barredo Valenzuela. Separation of molybdenum and cobalt from spent catalyst using Cyanex 272 and Cyanex 301. By kadambini sarangi.

Recovery of Molybdenum Rhenium From

2017. 5. 22. Molybdenum-rhenium extraction was unaffected by presence of chalcopyrite in the molybdenite concentrate; however, molybdenum extraction declines if the copper content, as chalcocite, exceeds 7 pct. High-purity molybdenum and rhenium compounds can be recovered from the electrolyzed reaction mass by liquid-solid separation, solvent extraction

Recovery and Separation of Molybdenum and Rhenium

Recovery and separation of molybdenum and rhenium from a process solution was accomplished by a technique developed by the Federal Bureau of Mines involving a combined solvent extraction and activated carbon adsorption procedure. The processing sequence required treatment of the solution with SO2 to reduce the chlorate ion and adjust the pH prior to solvent extraction of molybdenum and rhenium

Selective Recovery of Molybdenum over Rhenium from Molybdenite

2020. 11. 4. Abstract: Selective solvent extraction of molybdenum over rhenium from molybdenite (MoS2) ﬂue dust leaching solution was studied. In the present work, thermodynamic calculations of the chemical equilibria in aqueous solution were ﬁrst performed, and the potential–pH diagram for the Mo–Re–SO2 4 –H2O system was constructed.

Separation and Puriﬁcation Technology

Rhenium Molybdenum Roasting ﬂue-dust TBP Solvent extraction ABSTRACT The selective extraction of rhenium from the leach liquor of molybdenite roasting ﬂue-dust and its subsequent stripping were investigated using the solvent extraction

Recovery of molybdenum and rhenium in scrub liquors

Abstract The present work addresses the recovery of rhenium from scrub liquor of molybdenite concentrate roasting fume and dust by solvent extraction method. According to the results, recovery of rhenium from the scrub liquor is not practical unless molybdenum is removed in advance. The extraction of molybdenum was carried out using a D2EHPA-TBP system which resulted in up to

Extraction of Molybdenum from Molybdenite

2012. 9. 19. Molybdenite concentrates are usually treated by roasting, but low-concentration SO2 pollution is an associated problem. A hydrometallurgical process with pressure oxidation leaching (POX) and solvent extraction (SX) was developed in recent years. During POX, the oxidation of molybdenum (Mo) is above 98%. than 95% of the rhenium (Re) and 15% to 20% of the Mo are leached into

Extraction of molybdenum by a supported liquid membrane

2014. 3. 12. Extraction of molybdenum by a supported liquid membrane method Carlos Basualtoa,*, Jose´ Marcheseb, Fernando Valenzuelaa, Adolfo Acostab a Lab. Operaciones Unitarias, Fac. Ciencias Quı´micas y Farmace´uticas, Universidad de Chile, CC 233, Santiago, Chile b Laboratorio de Ciencias de Superﬁcie y Medios Porosos, Dpto de Quı´mica, UNSL-FONCYT, C.C.256-5700, San Luis, Argentina

US3739057A Process for the recovery of rhenium and

process for the recovery of molybdenum and rhenium from molybdenite which comprises: oxidizing the molybdenum in the molybdenite concentrate slurry to the hexavalent from with oxygen or oxygen-containing gases and less than a stoichiometric amount of nitric acid for the sulfide sulfur present, recovering molybdenum and rhenium values from the resulting solution when it contains up to 600

(PDF) Extraction of molybdenum by a supported liquid

Extraction of molybdenum by a supported liquid membrane method. Fernando Valenzuela. Related Papers. Transport of molybdenum with Alamine 336 using supported liquid membrane. By Fernando Barredo Valenzuela. Separation of molybdenum and cobalt from spent catalyst using Cyanex 272 and Cyanex 301. By kadambini sarangi.

Separation of Rhenium (VII) and Vanadium (V) from Hydrochloric

2017. 9. 28. high extraction efficiency for rhenium and vanadium from these solutions [15,16,25,26]. However, little information has been reported on the separation of V(V) and Re(VII) from hydrochloric acid solutions by neutral extractants. over, the stripping of metals from the loaded TBP is fairly easy [13]. Therefore, in this work, TBP was employed to

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